Maintenance and Repair
Many of the maintenance and repair techniques described in the Brief,
particularly those relating to cleaning and painting, are potentially dangerous
and should be carried out only by experienced and qualified workmen using
protective equipment suitable to the task. In all but the most simple repairs,
it is best to involve a preservation architect or building conservator
to assess the condition of the iron and prepare contract documents for
its treatment.
As with any preservation project, the work must be preceded by a review
of local building codes and environmental protection regulations to determine
whether any conflicts exist with the proposed treatments. If there are
conflicts, particularly with cleaning techniques or painting materials,
then waivers or variances need to be negotiated, or alternative treatments
or materials adopted.
Common problems encountered today with cast-iron construction include
badly rusted or missing elements, impact damage, structural failures, broken
joints, damage to connections, and loss of anchorage in masonry.
Oxidation, or rusting, occurs rapidly when cast iron is exposed to moisture
and air. The minimum relative humidity necessary to promote rusting is
65%, but this figure can be lower in the presence of corrosive agents,
such as sea water, salt air, acids, acid precipitation, soils, and some
sulfur compounds present in the atmosphere, which act as catalysts in the
oxidation process. Rusting is accelerated in situations where architectural
details provide pockets or crevices to trap and hold liquid corrosive agents.
Furthermore, once a rust film forms, its porous surface acts as a reservoir
for liquids, which in turn causes further corrosion. If this process is
not arrested, it will continue until the iron is entirely consumed by corrosion,
leaving nothing but rust.
Structural crack, gaps at joints between components, and a large opening where part of the console bracket is missing are the problems evident in this cast-iron assembly. Photo: Ford, Powell & Carson.
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Galvanic corrosion is an electrochemical action that results when two
dissimilar metals react together in the presence of an electrolyte, such
as water containing salts or hydrogen ions. The severity of the
galvanic corrosion is based on the difference in potential between the
two metals, their relative surface areas, and time. If the more noble metal
(higher position in electrochemical series) is much larger in area than
the baser, or less noble, metal, the deterioration of the baser metal will
be more rapid and severe. If the more noble metal is much smaller in area
than the baser metal, the deterioration of the baser metal will be much
less significant. Cast iron will be attacked and corroded when it is adjacent
to more noble metals such as lead or copper.
Graphitization of cast iron, a less common problem, occurs in the presence
of acid precipitation or seawater. As the iron corrodes, the porous graphite
(soft carbon) corrosion residue is impregnated with insoluble corrosion
products. As a result, the cast-iron element retains its appearance and
shape but is weaker structurally. Graphitization occurs where cast iron
is left unpainted for long periods or where caulked joints have failed
and acidic rainwater has corroded pieces from the backside. Testing and
identification of graphitization is accomplished by scraping through the
surface with a knife to reveal the crumbling of the iron beneath. Where
extensive graphitization occurs, usually the only solution is replacement
of the damaged element.
Castings may also be fractured or flawed as a result of imperfections
in the original manufacturing process, such as air holes, cracks, and cinders,
or cold shuts (caused by the "freezing" of the surface of the
molten iron during casting because of improper or interrupted pouring).
Brittleness is another problem occasionally found in old cast-iron elements.
It may be a result of excessive phosphorus in the iron, or of chilling
during the casting process.